A6283
乙酸
glacial, ReagentPlus, ≥99%
別名:
冰乙酸
線性分子式:
CH3CO2H
CAS號:
64-19-7
分子量:
60.05
Beilstein:
506007
EC 號:
200-580-7
MDL編號:
MFCD00036152
PubChem化學物質編號:
329770889
屬性
蒸汽密度
2.07 (vs air)
質量水平
200
產品線
ReagentPlus
測定
≥99%
形式
liquid
自燃溫度
800°F
expl. lim.
16%, 92°F
4%, 59°F
折射率
n20/D 1.371 (lit.)
pH值(酸堿度)
2.5 (20°C, 50g/L)
bp
117-118°C (lit.)
mp
16.2°C (lit.)
溶解性
alcohol: miscible(lit.)
carbon disulfide: insoluble(lit.)
glycerol: miscible(lit.)
water: miscible(lit.)
密度
1.049g/mLat 25°C (lit.)
儲存溫度
room temp
SMILES string
CC(O)=O
InChI
1S/C2H4O2/c1-2(3)4/h1H3,(H,3,4)
InChI key
QTBSBXVTEAMEQO-UHFFFAOYSA-N
說明
一般描述
乙酸是一種脂肪族有機酸。[1]這是一種易吸濕的腐蝕性液體,有一種類似醋的氣味。[1][2]它可以在錳或鈷鹽存在下氧化乙醛合成。[2]用于乙酸酐、醋酸纖維素和乙酸酯的合成。[2]已有關于它對紙張老化的影響的研究。[3]
應用
Acetic acid (AcOH) can be used as:
A reaction solvent in many organic reactions such as bromination, hydrolysis, solvolysis, reductions, and hydrogenations.
A reagent in the protonolysis of organometallic compounds.
An acetylating agent for the acetylation of electron-rich aromatic compounds.
A catalyst to synthesize di(indolyl)methanes by the condensation reaction of indole and aromatic aldehydes.
A solvent system to prepare 3,4-dihydropyrimidin-2(1H)-one derivative via Biginelli reaction of aromatic aldehydes, 1,3-dicarbonyl compounds, and urea in the presence of a boric acid catalyst.
Acetic acid can also be used in the following:
Manganese(III) acetate/AcOH catalytic system is used in the conversion of alkenes to lactones.
Iron salts/AcOH is used to oxidize 2-methylnaphthalene to 2-methyl-1-naphthol in the presence of H2O2.
包裝
100, 100, 500 mL in glass bottle
1, 2.5 L in glass bottle
18 L in poly drum
特點和優(yōu)勢
Good stability towards many reagents
Excellent solubility of organic compounds in this reagent